KFU. Card publication. Synthesis and spectroscopic characterization of Ru(II) and Sn(IV)-porphyrins supramolecular complexes

KAZAN
FEDERAL UNIVERSITY

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SYNTHESIS AND SPECTROSCOPIC CHARACTERIZATION OF RU(II) AND SN(IV)-PORPHYRINS SUPRAMOLECULAR COMPLEXES

Form of presentation

Articles in international journals and collections

Year of publication

2015

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Authors, employees of KFU

Khodov Ilya Anatolevich, author

Bibliographic description in the original language

Synthesis and spectroscopic characterization of Ru(II) and Sn(IV)-porphyrins supramolecular complexes

Annotation

Synthesis and NMR studies of Ru(II) and Sn(IV) tetraphenylporphyrins supramolecular complexes were carried out. The diffusion coefficients of the complexes, porphyrinates, and solvents were determined by DOSY NMR spectroscopy. By the method of spectrophotometric titration a binding ability of Ru(II) tetraphenylporphyrin towards 4-(imidazol-1-yl)-phenol was investigated, stability constant of resulting complexes and concentration intervals of their existence were defined. Crown Copyright ? 2014 Published by Elsevier B.V. All rights reserved.

Keywords

DOSY, COSY, NMR.Axial coordination, Organic substrate, Ru(II) porphyrins, Sn(IV) porphyrins, Supramolecular complexes.

The name of the journal

JOURNAL OF MOLECULAR STRUCTURE

Please use this ID to quote from or refer to the card

https://repository.kpfu.ru/eng/?p_id=120986&p_lang=2

Full metadata record

Field DC	Value	Language
dc.contributor.author	Khodov Ilya Anatolevich	ru_RU
dc.date.accessioned	2015-01-01T00:00:00Z	ru_RU
dc.date.available	2015-01-01T00:00:00Z	ru_RU
dc.date.issued	2015	ru_RU
dc.identifier.citation	Synthesis and spectroscopic characterization of Ru(II) and Sn(IV)-porphyrins supramolecular complexes	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/eng/?p_id=120986&p_lang=2	ru_RU
dc.description.abstract	JOURNAL OF MOLECULAR STRUCTURE	ru_RU
dc.description.abstract	Synthesis and NMR studies of Ru(II) and Sn(IV) tetraphenylporphyrins supramolecular complexes were carried out. The diffusion coefficients of the complexes, porphyrinates, and solvents were determined by DOSY NMR spectroscopy. By the method of spectrophotometric titration a binding ability of Ru(II) tetraphenylporphyrin towards 4-(imidazol-1-yl)-phenol was investigated, stability constant of resulting complexes and concentration intervals of their existence were defined. Crown Copyright ? 2014 Published by Elsevier B.V. All rights reserved.	ru_RU
dc.language.iso	ru	ru_RU
dc.subject	DOSY	ru_RU
dc.subject	COSY	ru_RU
dc.subject	NMR.Axial coordination	ru_RU
dc.subject	Organic substrate	ru_RU
dc.subject	Ru(II) porphyrins	ru_RU
dc.subject	Sn(IV) porphyrins	ru_RU
dc.subject	Supramolecular complexes.	ru_RU
dc.title	Synthesis and spectroscopic characterization of Ru(II) and Sn(IV)-porphyrins supramolecular complexes	ru_RU
dc.type	Articles in international journals and collections	ru_RU