KFU. Card publication. Dynamic NMR study of cyclic derivatives of pyridoxine

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FEDERAL UNIVERSITY

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DYNAMIC NMR STUDY OF CYCLIC DERIVATIVES OF PYRIDOXINE

Form of presentation

Articles in international journals and collections

Year of publication

2015

Язык

русский

Authors, employees of KFU

Klochkova Evelina Andreevna, author

Authors, postgraduates KFU

Rakhmatullin Ilfat Zufarovich, postgraduate kfu

Bibliographic description in the original language

Rakhmatullin I.Z. Dynamic NMR study of cyclic derivatives of pyridoxine / I.Z. Rakhmatullin, L.F. Galiullina, M.R. Garipov, A.D. Strel?nik, Y.G. Shtyrlin, V.V. Klochkov // Magnetic resonance in chemistry. - 2014. - V. 52 (12). - P. 769-778.

Annotation

A series of pyridoxine derivatives was investigated by 1H and 2D nuclear overhauser enhancement spectroscopy (NOESY) NMR. The free energies of activation for the pyridyl-oxygen rotation of the 2,4-dinitrophenyl ether of the seven-membered acetals of pyridoxine were measured by dynamic NMR. A conformational exchange between the chair and twist forms of the seven-membered acetal ring was confirmed by dynamic NMR and STO3G computations.

Keywords

dynamic 1H NMR, energy barrier, pyridoxine

The name of the journal

Magnetic resonance in chemistry

URL

http://onlinelibrary.wiley.com/doi/10.1002/mrc.4123/abstract

Please use this ID to quote from or refer to the card

https://repository.kpfu.ru/eng/?p_id=113683&p_lang=2

Full metadata record

Field DC	Value	Language
dc.contributor.author	Klochkova Evelina Andreevna	ru_RU
dc.contributor.author	Rakhmatullin Ilfat Zufarovich	ru_RU
dc.date.accessioned	2015-01-01T00:00:00Z	ru_RU
dc.date.available	2015-01-01T00:00:00Z	ru_RU
dc.date.issued	2015	ru_RU
dc.identifier.citation	Rakhmatullin I.Z. Dynamic NMR study of cyclic derivatives of pyridoxine / I.Z. Rakhmatullin, L.F. Galiullina, M.R. Garipov, A.D. Strel?nik, Y.G. Shtyrlin, V.V. Klochkov // Magnetic resonance in chemistry. - 2014. - V. 52 (12). - P. 769-778.	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/eng/?p_id=113683&p_lang=2	ru_RU
dc.description.abstract	Magnetic resonance in chemistry	ru_RU
dc.description.abstract	A series of pyridoxine derivatives was investigated by 1H and 2D nuclear overhauser enhancement spectroscopy (NOESY) NMR. The free energies of activation for the pyridyl-oxygen rotation of the 2,4-dinitrophenyl ether of the seven-membered acetals of pyridoxine were measured by dynamic NMR. A conformational exchange between the chair and twist forms of the seven-membered acetal ring was confirmed by dynamic NMR and STO3G computations.	ru_RU
dc.language.iso	ru	ru_RU
dc.subject	dynamic 1H NMR	ru_RU
dc.subject	energy barrier	ru_RU
dc.subject	pyridoxine	ru_RU
dc.title	Dynamic NMR study of cyclic derivatives of pyridoxine	ru_RU
dc.type	Articles in international journals and collections	ru_RU