KFU. Card publication. Twice as smart behavior of tert-butylthiacalix[4]arene derivative in glassy and crystalline form

KAZAN
FEDERAL UNIVERSITY

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TWICE AS SMART BEHAVIOR OF TERT-BUTYLTHIACALIX[4]ARENE DERIVATIVE IN GLASSY AND CRYSTALLINE FORM

Form of presentation

Articles in international journals and collections

Year of publication

2015

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Authors, employees of KFU

Gataullina Karina Vsevolodovna, author

Gorbachuk Valeriy Vilenovich, author

Stoykov Ivan Ivanovich, author

Other authors

Gubaydullin Aydar Timergaleevich, author

Authors, postgraduates KFU

Gataullina Karina Vsevolodovna, postgraduate kfu

Bibliographic description in the original language

Gataullina, K. V. Twice as smart behavior of tert-butylthiacalix[4]arene derivative in glassy and crystalline form / K. V. Gataullina, M.Ziganshin, I. Stoikov, A. T. Gubaidullin, V.V. Gorbatchuk, // Physical Chemistry Chemical Physics. - 2015. - V.17.- N24. - P.15887-15895.

Annotation

A studied tert-butylthiacalix[4]arene derivative with four N-(2-acetoxyethyl)carbamoylmethoxy substituents on its lower rim in partial-cone configuration (calixarene 1) can remember its previous treatment in three essentially different ways by the formation either of a molecular glass or two metastable polymorphs after heating or the removal of an included guest molecule. Guest-induced memory is very selective with a polymorph created only after the release of a few included guests among a large series of those studied and is detected via an exothermic transition. Along with ordinary properties, like glass transition, curing and cold crystallization, the molecular glass from 1 is selective due to its ability to crystallize in solvent vapors and vapor mixtures over a well-defined concentration range. Being cooperative, this property may be used for the visual detection of ethanol content in water solution when it reaches a threshold value.

Keywords

molecular glass, smart materials, calixarene, thermal analysis

The name of the journal

PHYS CHEM CHEM PHYS

URL

http://pubs.rsc.org/en/content/articlepdf/2015/cp/c5cp02042e

Please use this ID to quote from or refer to the card

https://repository.kpfu.ru/eng/?p_id=107727&p_lang=2

Full metadata record

Field DC	Value	Language
dc.contributor.author	Gataullina Karina Vsevolodovna	ru_RU
dc.contributor.author	Gorbachuk Valeriy Vilenovich	ru_RU
dc.contributor.author	Stoykov Ivan Ivanovich	ru_RU
dc.contributor.author	Gubaydullin Aydar Timergaleevich	ru_RU
dc.contributor.author	Gataullina Karina Vsevolodovna	ru_RU
dc.date.accessioned	2015-01-01T00:00:00Z	ru_RU
dc.date.available	2015-01-01T00:00:00Z	ru_RU
dc.date.issued	2015	ru_RU
dc.identifier.citation	Gataullina, K. V. Twice as smart behavior of tert-butylthiacalix[4]arene derivative in glassy and crystalline form / K. V. Gataullina, M.Ziganshin, I. Stoikov, A. T. Gubaidullin, V.V. Gorbatchuk, // Physical Chemistry Chemical Physics. - 2015. - V.17.- N24. - P.15887-15895.	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/eng/?p_id=107727&p_lang=2	ru_RU
dc.description.abstract	PHYS CHEM CHEM PHYS	ru_RU
dc.description.abstract	A studied tert-butylthiacalix[4]arene derivative with four N-(2-acetoxyethyl)carbamoylmethoxy substituents on its lower rim in partial-cone configuration (calixarene 1) can remember its previous treatment in three essentially different ways by the formation either of a molecular glass or two metastable polymorphs after heating or the removal of an included guest molecule. Guest-induced memory is very selective with a polymorph created only after the release of a few included guests among a large series of those studied and is detected via an exothermic transition. Along with ordinary properties, like glass transition, curing and cold crystallization, the molecular glass from 1 is selective due to its ability to crystallize in solvent vapors and vapor mixtures over a well-defined concentration range. Being cooperative, this property may be used for the visual detection of ethanol content in water solution when it reaches a threshold value.	ru_RU
dc.language.iso	ru	ru_RU
dc.subject	molecular glass	ru_RU
dc.subject	smart materials	ru_RU
dc.subject	calixarene	ru_RU
dc.subject	thermal analysis	ru_RU
dc.title	Twice as smart behavior of tert-butylthiacalix[4]arene derivative in glassy and crystalline form	ru_RU
dc.type	Articles in international journals and collections	ru_RU