KFU. Card publication. Determination of fluoroquinolone antibiotics through the fluorescent response of Eu(III) based nanoparticles fabricated by layer-by-layer technique Nikolay Davydova, Rustem Zairova, Asiya Mustafinaa,∗, Viktor Syakayeva, Dmitry Tatarinova, Vladimir Mironova, Sergei Ereminb, Alexander Konovalova, Marat Mustafinc a A.E. Arbuzov Institute of Organic and Physical Chemistry, Arbuzov Street, 8, Kazan, Russia b Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow 119991, Russia c Kazan (Volga Region) Federal University, Kremlevskaya Street, 18, Kazan 420008, Russia

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DETERMINATION OF FLUOROQUINOLONE ANTIBIOTICS THROUGH THE FLUORESCENT RESPONSE OF EU(III) BASED NANOPARTICLES FABRICATED BY LAYER-BY-LAYER TECHNIQUE NIKOLAY DAVYDOVA, RUSTEM ZAIROVA, ASIYA MUSTAFINAA,∗, VIKTOR SYAKAYEVA, DMITRY TATARINOVA, VLADIMIR MIRONOVA, SERGEI EREMINB, ALEXANDER KONOVALOVA, MARAT MUSTAFINC A A.E. ARBUZOV INSTITUTE OF ORGANIC AND PHYSICAL CHEMISTRY, ARBUZOV STREET, 8, KAZAN, RUSSIA B DEPARTMENT OF CHEMISTRY, M.V. LOMONOSOV MOSCOW STATE UNIVERSITY, MOSCOW 119991, RUSSIA C KAZAN (VOLGA REGION) FEDERAL UNIVERSITY, KREMLEVSKAYA STREET, 18, KAZAN 420008, RUSSIA

Form of presentation

Articles in international journals and collections

Year of publication

2013

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Authors, employees of KFU

Mustafin Marat Rafaelevich, author

Mustafina Asiya Rafaelevna, author

Other authors

Davydov Nikolay Petrovich, author

Bibliographic description in the original language

The present work introduces the determination of fluoroquinolone antibiotics (FQs) in aqueous solutions through the fluorescent response of Eu(TTA)3 and [Eu(TTA)31] (TTA− and 1 are thenoyltrifluoroacetonate and phosphine oxide derivative) complexes encapsulated into the polyelectrolyte capsules fabricated through layer-by-layer deposition of poly(sodium 4-styrenesulfonate)(PSS) and polyethyleneimine (PEI). The variation of luminescent core, polyelectrolyte deposition and concentration conditions reveals two modes of fluorescent response on FQs of diverse structure namely the sensitization and quenching of Eu(III) centered luminescence. The obtained regularities reveal the ternary complex formation and the ligand exchange occurring at the interface of polyelectrolyte coated [Eu(TTA)31] based colloids as the reasons of the diverse fluorescent response of Eu(III) centered luminescence on FQs. The factors affecting the fluorescent response have been revealed.

Annotation

Analytica Chimica Acta

Keywords

Fluoroquinolones Luminescence Europium(III) Nanoparticles Capsules Layer-by-layer

The name of the journal

Analytica Chimica Acta

URL

http://www.journals.elsevier.com/analytica-chimica-acta

Please use this ID to quote from or refer to the card

https://repository.kpfu.ru/eng/?p_id=105610&p_lang=2

Full metadata record

Field DC	Value	Language
dc.contributor.author	Mustafin Marat Rafaelevich	ru_RU
dc.contributor.author	Mustafina Asiya Rafaelevna	ru_RU
dc.contributor.author	Davydov Nikolay Petrovich	ru_RU
dc.date.accessioned	2013-01-01T00:00:00Z	ru_RU
dc.date.available	2013-01-01T00:00:00Z	ru_RU
dc.date.issued	2013	ru_RU
dc.identifier.citation	The present work introduces the determination of fluoroquinolone antibiotics (FQs) in aqueous solutions through the fluorescent response of Eu(TTA)3 and [Eu(TTA)31] (TTA− and 1 are thenoyltrifluoroacetonate and phosphine oxide derivative) complexes encapsulated into the polyelectrolyte capsules fabricated through layer-by-layer deposition of poly(sodium 4-styrenesulfonate)(PSS) and polyethyleneimine (PEI). The variation of luminescent core, polyelectrolyte deposition and concentration conditions reveals two modes of fluorescent response on FQs of diverse structure namely the sensitization and quenching of Eu(III) centered luminescence. The obtained regularities reveal the ternary complex formation and the ligand exchange occurring at the interface of polyelectrolyte coated [Eu(TTA)31] based colloids as the reasons of the diverse fluorescent response of Eu(III) centered luminescence on FQs. The factors affecting the fluorescent response have been revealed.	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/eng/?p_id=105610&p_lang=2	ru_RU
dc.description.abstract	Analytica Chimica Acta	ru_RU
dc.description.abstract	Analytica Chimica Acta	ru_RU
dc.description.abstract	? Novel route of fluorescent determination of fluoroquinolones was developed.	ru_RU
dc.language.iso	ru	ru_RU
dc.subject		ru_RU
dc.title	Determination of fluoroquinolone antibiotics through the fluorescent response of Eu(III) based nanoparticles fabricated by layer-by-layer technique Nikolay Davydova, Rustem Zairova, Asiya Mustafinaa,∗, Viktor Syakayeva, Dmitry Tatarinova, Vladimir Mironova, Sergei Ereminb, Alexander Konovalova, Marat Mustafinc a A.E. Arbuzov Institute of Organic and Physical Chemistry, Arbuzov Street, 8, Kazan, Russia b Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow 119991, Russia c Kazan (Volga Region) Federal University, Kremlevskaya Street, 18, Kazan 420008, Russia	ru_RU
dc.type	Articles in international journals and collections	ru_RU