KFU. Card publication. Reversible thermal carbon–hydrogen bond cleavage in alkanes and arenes with dihalogenobis(triphenylphosphine)palladium(II) complexes

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REVERSIBLE THERMAL CARBON&NDASH;HYDROGEN BOND CLEAVAGE IN ALKANES AND ARENES WITH DIHALOGENOBIS(TRIPHENYLPHOSPHINE)PALLADIUM(II) COMPLEXES

Form of presentation

Articles in international journals and collections

Year of publication

1994

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Authors, employees of KFU

Kuramshin Arkadiy Iskanderovich, author

Solomonov Boris Nikolaevich, author

Bibliographic description in the original language

Reversible thermal carbon–hydrogen bond cleavage in alkanes and arenes with dihalogenobis(triphenylphosphine)palladium(II) complexes Andrei N. Vedernikov, Arkadii I. Kuramshin and Boris N. Solomonov // J. Chem. Soc., Chem. Commun., 1994, 121-122; DOI: 10.1039/C39940000121

Annotation

Dihalogenobis(triphenylphosphine)palladium(II) complexes 1, PdX2(PPh3)2(X = Cl, Br, I), reacts reversibly with saturated and aromatic hydrocarbons RH (RH =p-xylene, toluene, benzene, n-hexane, cyclohexane), slowly at ambient temperature and rapidly on heating at 70?130 ?C, to produce hydridodihalogeno(organo)bis(triphenylphosphine)-palladium(IV) complexes 2, Pd(H)(R)X2(PPh3)2; in the presence of bases complexes 2 eliminate hydrogen halide forming organobis(triphenylphosphine)palladium(II) halide 3, Pd(R)X(PPh3)2.

Keywords

Dihalogenobis(triphenylphosphine)palladium(II) complexes �-H activation

The name of the journal

Chemical communications (�� J. Chem. Soc., Chem. Commun.)

URL

http://pubs.rsc.org/en/content/articlelanding/1994/c3/c39940000121#!divAbstract

Please use this ID to quote from or refer to the card

https://repository.kpfu.ru/eng/?p_id=105214&p_lang=2

Full metadata record

Field DC	Value	Language
dc.contributor.author	Kuramshin Arkadiy Iskanderovich	ru_RU
dc.contributor.author	Solomonov Boris Nikolaevich	ru_RU
dc.date.accessioned	1994-01-01T00:00:00Z	ru_RU
dc.date.available	1994-01-01T00:00:00Z	ru_RU
dc.date.issued	1994	ru_RU
dc.identifier.citation	Reversible thermal carbon–hydrogen bond cleavage in alkanes and arenes with dihalogenobis(triphenylphosphine)palladium(II) complexes Andrei N. Vedernikov, Arkadii I. Kuramshin and Boris N. Solomonov // J. Chem. Soc., Chem. Commun., 1994, 121-122; DOI: 10.1039/C39940000121	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/eng/?p_id=105214&p_lang=2	ru_RU
dc.description.abstract	Chemical communications (�� J. Chem. Soc., Chem. Commun.)	ru_RU
dc.description.abstract	Dihalogenobis(triphenylphosphine)palladium(II) complexes 1, PdX2(PPh3)2(X = Cl, Br, I), reacts reversibly with saturated and aromatic hydrocarbons RH (RH =p-xylene, toluene, benzene, n-hexane, cyclohexane), slowly at ambient temperature and rapidly on heating at 70?130 ?C, to produce hydridodihalogeno(organo)bis(triphenylphosphine)-palladium(IV) complexes 2, Pd(H)(R)X2(PPh3)2; in the presence of bases complexes 2 eliminate hydrogen halide forming organobis(triphenylphosphine)palladium(II) halide 3, Pd(R)X(PPh3)2.	ru_RU
dc.language.iso	ru	ru_RU
dc.subject		ru_RU
dc.title	Reversible thermal carbon–hydrogen bond cleavage in alkanes and arenes with dihalogenobis(triphenylphosphine)palladium(II) complexes	ru_RU
dc.type	Articles in international journals and collections	ru_RU