KAZAN
FEDERAL UNIVERSITY
Khayarov Khasan Rafaelevich
Positions
инженер-проектировщик,
Head University
/
Alexander Butlerov Institute of Chemistry
/ Отдел органической химии / лаборатория исследований органических соединений (основной работник)
engineer category 1,
Head University
/
Alexander Butlerov Institute of Chemistry
/
Department of High Molecular and Organoelement Compounds
(внутренний совместитель)
Research work
02.00.03 - Organic Chemistry
02.00.01 - Inorganic Chemistry
02.00.08 - Chemistry of Organoelement Compounds
Performance
Quantity of published work in Scopus:
51
Quantity of reference on published work in Scopus:
268
Personal index of Hirsh:
6
Performance
2024
Larionov R.A, Ziganshina S.A, Khayarov K.R, A new insight into the mechanism of solid-state cyclization of dipeptides: The effect of the sequence of amino acid residues in phenylalanyl-leucine and leucyl-phenylalanine//Thermochimica Acta. - 2024. - Vol.731, Is.. - Art. №179645.
Mirgazieva E.R, Larionov R.A, Ziganshina S.A, Khayarov Kh.R, Gorbatchuk V.V, Ziganshin M.A Cyclization of the l-alanyl-l-isoleucine dipeptide in the solid state: effect of the amino acid sequence on the reaction kinetics // Russian Chemical Bulletin. - 2024. - Vol.73, Is.3. - P.514-522.
Salin A.V, Shabanov A.A, Khayarov Kh.R, Islamov D.R, Voloshina A.D, Amerhanova S.K, Lyubina A.P. Phosphine-Catalyzed Synthesis and Cytotoxic Evaluation of Michael Adducts of the Sesquiterpene Lactone Arglabin//ChemMedChem. - 2024. - Vol., Is.. - .
D.A.Tatarinov, E.A.Mikulenkova, I.Litvinov, K.Khayarov and V.F.Mironov. Divergent synthesis of oxaphospholenes and phosphacoumarines via the reaction of 2-alkenylphenols with PCl3 or PCl5. // Org. Biomol. Chem. 2024. Vol. 22. No. 8. P. 1629-1633. Doi 10.1039/D3OB01718D.
2023
Il'in A.V, Khayarov K.R, Anisimova K.S, Phosphine-Catalyzed ?- and Vicinal Bis-Addition of P(O)H Compounds to Alkynoates//ChemistrySelect. - 2023. - Vol.8, Is.1. - Art. №e202204002.
Gafurov Z.N, Sakhapov I.F, Kagilev A.A, Kantyukov A.O, Mikhailov I.K, Ganeev, G.R, Faizullin R.R, Khayarov Kh.R, Gerasimov A.V, Yakhvarov D.G. SYNTHESIS, STRUCTURE, AND PROPERTIES OF THE ORGANONICKEL ?-COMPLEX [NiBr(Pmp)(bpy)], WHERE Pmp IS 2,3,4,5,6- PENTAMETHYLPHENYL, bpy IS 2,2?-BIPYRIDINE//Journal of Structural Chemistry. - 2023. - Vol.64, Is.1. - P.121-130.
Larionov R.A, Ziganshina S.A, Klimovitskii A.E, Khayarov Kh.R, Babaeva O.B, Gorbachuk V.V, Ziganshin, M.A. Cyclization of L-Leucyl-L-valine Dipeptide in the Crystal Phase under Non-Isюthermal Conditions // Russian Journal of General Chemistry. - 2023. - Vol.93, Is.11. - P.2775-2784.
Salin A.V, Shabanov A.A, Khayarov K.R, Stereoelectronic Effect in the Reaction of ?-Methylene Lactones with Tertiary Phosphines and Its Application in Organocatalysis//Journal of Organic Chemistry. - 2023. - Vol.88, Is.16. - P.11954-11967.
Gorbachuk Elena, Grell T, Khayarov Khasan, Molybdenum-Mediated Insertion of Ketones into the P-P bond of cyclo-(P5Ph5) and Formation of Trinuclear Molybdenum Complexes//CHEMPLUSCHEM. - 2023. - Vol.88, Is.8. - Art. №e202300251.
2022
Catalytic performance of nickel(II) complexes bearing 1,10-phenanthroline based ligands in homogeneous ethylene oligomerization // G.E. Bekmukhamedov, A.V. Sukhov, A.M. Kuchkaev, A.M. Kuchkaev, K.R. Khayarov, A.B. Dobrynin, V.M. Babaev, D.G. Yakhvarov // Polyhedron. – 2022. – 223. – 115978. https://doi.org/10.1016/j.poly.2022.115978
Terekhova, N. V.; Lyubina, A.P.; Voloshina, A.D.; Sapunova, A.S.; Khayarov, K.R.; Islamov, D.R.; Usachev, K.S.; Evtugyn, V.G.; Tatarinov, D.A.; Mironov, V.F. Synthesis, Biological Evaluation and Structure-Activity Relationship of 2-(2-Hydroxyaryl)Alkenylphosphonium Salts with Potency as Anti-MRSA Agents. Bioorg. Chem. 2022, 127, 106030.
Influence of N- and P-substituents in N-aryl-phosphinoglycine ligands on selectivity of Ni-catalysed ethylene oligomerization / A.A. Kagileva, A.A. Kagilev, A.O. Kantyukov, Z.N. Gafurov, I.F. Sakhapov, G.E. Bekmukhamedov, K.R. Khayarov, E.M. Zueva, O.S. Soficheva, D.G. Yakhvarov // New J. Chem., 2022.
Kuchkaev A.M, Kuchkaev A.M, Khayarov Kh.R, Zueva, E. M., Dobrynin, A. B., Islamov, D. R., & Yakhvarov, D. G. PNP Ligands in Cobalt-Mediated Activation and Functionalization of White Phosphorus//Angewandte Chemie - International Edition. - 2022. - Vol., Is.. - .
Larionov R.A, Akhmetshin S.R, Gerasimov A.V, Morozova, A. S., Ziganshina, S. A., Khayarov, Kh. R., Gorbatchuk V. V. & Ziganshin, M. A. Kinetics of the Solid-State Cyclization of Glycylglycine Dipeptide//Russian Journal of Organic Chemistry. - 2022. - Vol.58, Is.8. - P.1076-1083.
Mironov V.F, Ivkova G.A, Litvinov I.A, Islamov, D. R. & Khayarov, Kh. R. Dimerization of Intermediate P+?C?O? Dipolar Ions into Carbaphosphatrane Derivatives during Intramolecular Cyclization of 2-R-4,4-Bis(trifluoromethyl)benzo[f][1,3,2]dioxaphosphepin-5-ones//Russian Journal of Organic Chemistry. - 2022. - Vol.58, Is.8. - P.1099-1107.
Bekmukhamedov G.E, Sukhov A.V, Kuchkaev A.M, Catalytic performance of nickel(II) complexes bearing 1,10-phenanthroline based ligands in homogeneous ethylene oligomerization//Polyhedron. - 2022. - Vol.223, Is.. - Art. №115978.
2021
Khayarov K, Pyataev A, Saifutdinov A, Structural, magnetic and fluorescence characterization of europium(III) azomethine complexes with asymmetric ligands//Polyhedron. - 2021. - Vol.199, Is.. - Art. № 115092.
Kuchkaev A.M, Shmelev N.Y, Kuchkaev A.M, Hydrolysis of Element (White) Phosphorus under the Action of Heterometallic Cubane-Type Cluster {Mo
3
PdS
4
}//Molecules (Basel, Switzerland). - 2021. - Vol.26, Is.3. - .
Gafurov Z.N, Zueva E.M, Bekmukhamedov G.E, Benzothiazole- vs. pyrazole-based unsymmetrical (PCN) pincer complexes of nickel(II) as homogeneous catalysts in ethylene oligomerization//Journal of Organometallic Chemistry. - 2021. - Vol.949, Is.. - Art. № 121951.
Mironov V. F. The formation of cage phosphoranes and their rearrangements in the reactions of substituted 2-(3-oxo-3-phenyl)ethoxybenzo[d]-1,3, 2-dioxaphospholes with perfluorodiacetyl / V.F.Mironov, M.N.Dimukhametov, G.A.Ivkova, Kh.R.Khayarov, D.R Islamov, I.A. Litvinov // Chem. Commun. - 2021. - V. 57. - P. 8516 -8519. DOI: 10.1039/d1cc02941j
Mironov Vladimir F., Dimukhametov Mudaris N., Ivkova Gulnara A., The formation of cage phosphoranes and their rearrangements in the reactions of substituted 2-(3-oxo-3-phenyl)ethoxybenzo[d]-1,3,2-dioxaphospholes with perfluorodiacetyl//CHEMICAL COMMUNICATIONS. - 2021. - Vol.57, Is.68. - P.8516-8519.
Указание к лабораторным работам и семинарским занятия по фармацевтической химии (методы исследования лекарственных веществ): учебно-методическое пособие / И.В. Галкина, Ю.В. Бахтиярова, Р.Р. Давлетшин и др. - Казань: Издательство Казанского университета, 2021. - 74 с.
2020
Gafurov Z.N., Bekmukhamedov G.E., Kagilev A.A., Kantyukov A.O., Sakhapov I.F., Mikhailov I.K., Khayarov K.R., Zaripov R.B., Islamov D.R., Usachev K.S., Luconi L., Rossin A., Giambastiani G., Yakhvarov D.G. Unsymmetrical pyrazole-based PCN pincer NiII halides: Reactivity and catalytic activity in ethylene oligomerization // Journal of Organometallic Chemistry. 2020. V. 912. P. 121163. https://doi.org/10.1016/j.jorganchem.2020.121163.
Gafurov_J.Organomet.Chem_2020_121163__pervaya_stranica_.pdf
Gafurov Z.N, Bekmukhamedov G.E, Kagilev A.A, Unsymmetrical pyrazole-based PCN pincer NiII halides: Reactivity and catalytic activity in ethylene oligomerization//Journal of Organometallic Chemistry. - 2020. - Vol.912, Is.. - Art. № 121163.
Davletshin R, Khayarov K, Zykova K, Synthesis and crystal structure of new ligand - N-didodecylphosphinoxido-4-nitrobenzyledenetetradecylammonium-4-methylbenzenesulfonate//Journal of Organometallic Chemistry. - 2020. - Vol.913, Is.. - Art. № 121189.
Davletshin R. Synthesis and crystal structure of new ligand - N-didodecylphosphinoxido-4-nitrobenzyledenetetradecylammonium-4-methylbenzenesulfonate /Davletshin R., Khayarov Kh., Zykova K., Galkina I., Davletshina N., Ivshin K., Kataeva O. //Journal of Organometallic Chemistry. - 2020. - Vol.913, Art. № 121189.
Serov Nikita Yu., Shtyrlin Valery G., Khayarov Khasan R., The kinetics and mechanisms of reactions in the flow systems glycine-sodium trimetaphosphate-imidazoles: the crucial role of imidazoles in prebiotic peptide syntheses//AMINO ACIDS. - 2020. - Vol. 52, Is. 5. 811-821.
Gafurov Z.N, Sakhapov I.F, Kagilev A.A, The formation of mesitylphosphine and dimesitylphosphine in the reaction of organonickel sigma-complex [NiBr(Mes)(bpy)] (Mes = 2,4,6-trimethylphenyl, bpy = 2,2'-bipyridine) with phosphine PH
3
//Phosphorus, Sulfur and Silicon and the Related Elements. - 2020. - Vol., Is.. - .
Farhadian, A., Varfolomeev, M.A., Shaabani, A., Zaripova, Y.F., Yarkovoi, V.V., Khayarov, Kh.R. Inhibition Performance of Chitosan- graft-Polyacrylamide as an Environmentally Friendly and High-Cloud-Point Inhibitor of Nucleation and Growth of Methane Hydrate//Crystal Growth and Design. - 2020. - Vol.20, Is.3. - P.1771-1778.
2019
Galkina, I.V. The Pudovik reaction: the synthesis of bioactive α-aminophosphonates with long alkyl chains / I.V. Galkina, Kh.R. Khayarov, R.R. Davletshin, A.Z. Gaynullin, A.V. Gerasimov, M.P. Shulaeva, О.К. Pozdeev, S.N. Egorova, L.M. Usupova, and V.I. Galkin // Phosphorus, Sulfur, and Silicon and the Related Elements - 2019 - V. 194, Is 4-6, - P. 463-466
Bekmukhamedov, G.E. Electrochemical Synthesis of Zirconium Pre-Catalysts for Homogeneous Ethylene Oligomerization / Bekmukhamedov, G.E.; Sukhov, A.V.; Kuchkaev, A.M.; Khayarov, K.R.; Gerasimov, A.V.; Vasilenko, I.V.; Kostjuk, S.V.; Yakhvarov, D.G. // Catalysts - 2019. - V. 9 (№ 12). - P. 1059-.
F_catalysts_09_01059_pervaya_stranica.pdf
Zagumennov V.A, Sizova N.A, Khayarov Kh.R, Elucidation of the Structure of Products of Triphenylphosphine Electrooxidation in the Presence of Camphene//Russian Journal of General Chemistry. - 2019. - Vol.89, Is.9. - P.1777-1782.
Ziganshin, M.A., Larionov, R.A., Gerasimov, A.V., Ziganshina, S.A., Klimovitskii, A.E., Khayarov, Kh.R., Mukhametzyanov T.A., Gorbatchuk, V.V. Thermally induced cyclization of L‐isoleucyl‐L‐alanine in solid state: Effect of dipeptide structure on reaction temperature and self‐assembly // Journal of Peptide Science. - 2019. - Vol.25, Is.8. - Art. № e3177.
2018
EPR as a complimentary tool for the analysis of low-temperature oxidation reactions of crude oils
Dimukhametov M.N, Ivkova G.A, Khayarov K.R, Trimethylchlorosilane-Catalyzed Intramolecular Cyclization of 2-(2-Benzylideneaminoethyloxy)-1-phenylbenzo[e]-1,3,2-azaoxaphosphorin-4-one//Russian Journal of General Chemistry. - 2018. - Vol.88, Is.9. - P.1938-1940.
Mehrabi-Kalajahi S.S, Varfolomeev M.A, Yuan C, EPR as a complementary tool for the analysis of low-temperature oxidation reactions of crude oils//Journal of Petroleum Science and Engineering. - 2018. - Vol.169, Is.. - P.673-682.
2017
Khayarov, Kh.R. Synthesis of new Fluorescent Compounds from Substituted Benzaldehydes and Highest Amines / Kh.R. Khayarov, K.A. Ivshin, V.A. Burilov, A.V. Gerasimov, O.N. Kataeva, V.I. Galkin, I.V. Galkina // Тезисы докладов X Международной конференций молодых ученых по химии «Менделеев - 2017».- С.-Петербург, 4-7 апреля 2017.- С. 376.
Ziganshin Marat A., Safiullina Aisylu S., Gerasimov Alexander V., Thermally Induced Self-Assembly and Cyclization of L-Leucyl-L-Leucine in Solid State//JOURNAL OF PHYSICAL CHEMISTRY B. - 2017. - Vol.121, Is.36. - P.8603-8610.
2016
Serov N.Yu. Trimetaphosphate and imidazole - possible reagents in prebiotic peptide synthesis / N.Yu. Serov, V.G. Shtyrlin, Kh.R. Khayarov // The 21st International Conference on Phosphorus Chemistry. Abstracts book (Kazan, 5-10 June 2016). - Moscow, 2016. - P. 254.
First example of organonickel complex bearing three cyclic substituents in the σ-bonded aromatic ring: Bromo[(2,2' -bipyridine)-2,4,6-tricyclohexylphenylnickel] / Sakhapov I.F., Gafurov Z.N., Babaev V.M., RizvanovI.K., Dobrynin A.B., Krivolapov D.B., Khayarov K.R., Sinyashin, O.G. Yakhvarov, D.G. // Mendeleev Communications Volume 26, Issue 2, 2016, Pages 131-133
Gorbachuk E.V., Badeeva E.K., Katsyuba S.A., Pavlov P.O., Khayarov Kh.R., Sinyashin O.G., Yakhvarov D.G., Thermal stability of primary and secondary phosphine oxides formed as a reaction of phosphine oxide with ketones // Phosphorus, Sulfur Silicon Relat. Elem. –2016. – V. 191. – P. 1480-1481.
Серов Н.Ю. Квантово-химическое моделирование механизмов синтеза олигопептидов в системах аминокислота – триметафосфат натрия – имидазол / Н.Ю. Серов, В.Г. Штырлин // Сб. материалов X Всероссийской молодежной научно-инновационной школы «Математика и математическое моделирование» (Саров, 12-14 апреля 2016 г.). – Саров, 2016. – С. 132-133.
Серов Н.Ю. Структура комплексов меди(II), выращенных из ионной жидкости – ацетата 1-этил-3-имидазолия / Н.Ю. Серов, В.Г. Штырлин, Д.Р. Исламов, М.С. Бухаров // Тез. докл. XX Менделеевского съезда по общей и прикладной химии в 5 т. (Екатеринбург, 26-30 сентября 2016 г.). Т. 2b. – Екатеринбург: Уральское отделение РАН, 2016. – С. 90.
Serov N. Yu. Trimetaphosphate and imidazole - Possible reagents in prebiotic peptide synthesis / N. Yu. Serov, V. G. Shtyrlin, Kh. R. Khayarov // Phosphorus, Sulfur, and Silicon and the Related Elements. - 2016. - V. 191, N 11-12. - P. 1558-1559.
2014
Effect of a sacrificial anode material on the electrochemical generation of phosphane oxide (H3PO) / E.V. Gorbachuk, Kh.R. Khayarov, O.G. Sinyashin and D.G. Yakhvarov // Mendeleev Communications - 2014. 24 – P. 334–335
2006
Ziganshin, M.A. Guest exchange in dimeric capsules of a tetraurea calix[4]arene in the solid state / M. A. Ziganshin, L. S. Yakimova, Kh. R. Khayarov, V. V. Gorbatchuk, M. O. Vysotsky, V. Bohmer // Chem. Comm. - 2006. - P. 3897-3899
E-mail:
Khasan.Khayarov@kpfu.ru
Google scholar:
https://scholar.google.ru/citations?user=eaL7Sg4AAAAJ&hl=ru
Scientific and pedagogical experience:
3 г 1 м 8 д from 16.10.2021
General experience:
19 г 0 м 1 д from 02.07.2001
Experience in KFU:
5 г 7 м 0 д from 24.04.2019