Determination of a transparent conductive composite coating's conductivity type based on oriented platinum networks

G.R. Nizameeva a,b*, I.R. Nizameev a**, M.K. Kadirov a***

aArbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center,

Russian Academy of Sciences, Kazan, 420088 Russia

bKazan National Research Technological University, Kazan, 420015 Russia

E-mail: *guliya.riv@gmail.com, **irek.rash@gmail.com, ***kamaka59@gmail.com

Received December 23, 2022; Accepted January 25, 2023

 

ORIGINAL ARTICLE

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DOI: 10.26907/2542-064X.2023.1.23-36

For citation: Nizameeva G.R., Nizameev I.R., Kadirov M.K. Determination of a transparent conductive composite coating’s conductivity type based on oriented platinum networks. Uchenye Zapiski Kazanskogo Universiteta. Seriya Estestvennye Nauki, 2023, vol. 165, no. 1, pp. 23–36. doi: 10.26907/2542-064X.2023.1.23-36. (In Russian)

 

Abstract

This paper considers a method for determining the type of electrical conductivity of a previously developed composite transparent conductive coating based on oriented platinum networks embedded in the polymer matrix. Many researchers have recently been grappling with finding electrically conductive transparent coatings for smart devices with touch screens, particularly an alternative to the massively used indium tin oxide (ITO) having some disadvantages, the most serious of which is the lack of coating flexibility. The latter can be overcome by using various metal-polymer composites with high transparency in the optical range and low surface resistance. However, one should be aware that the type of conductivity depends on both the polymer matrix and the metal framework of a composite. This defines its electrical properties. Therefore, it is important to correctly identify and measure the electrical conductivity. The developed method is based on studying the temperature dependence of the surface resistance in the material.

Keywords: conductive coating, optical transparency, metal networks, oriented systems, platinum, poly(3,4-ethylenedioxythiophene) polystyrenesulfonate, polymer matrix, conductivity

Acknowledgements. This study was performed under the state assignment to the FRC Kazan Scientific Center, Russian Academy of Sciences.

Figure Captions

Fig. 1. Oriented networks on glass – optically transparent conductive coating.

Fig. 2. Structural formula of PEDOT.

Fig. 3 Structural formula of the PEDOT:PSS interpolymer complex.

Fig. 4. Unit for measuring the temperature dependence of the surface resistance of the optically transparent conductive coating.

Fig. 5. Four-probe measuring of the surface resistance.

Fig. 6. Temperature dependence of the surface resistance of the studied coating based on platinum nanonetworks.

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